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Issue 41, 2009
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Brønsted acid activation of α-diazo imide: a syn-selective glycolate Mannich reaction

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Abstract

A novel α-diazo imide reagent and its activation by strong Brønsted acid is shown to produce the product of a syn-glycolate Mannich transform with high diastereoselection.

Graphical abstract: Brønsted acid activation of α-diazo imide: a syn-selective glycolate Mannich reaction

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Publication details

The article was received on 10 Jul 2009, accepted on 28 Aug 2009 and first published on 14 Sep 2009


Article type: Communication
DOI: 10.1039/B913785H
Citation: Chem. Commun., 2009,0, 6195-6197
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    Brønsted acid activation of α-diazo imide: a syn-selective glycolate Mannich reaction

    T. L. Troyer, H. Muchalski and J. N. Johnston, Chem. Commun., 2009, 0, 6195
    DOI: 10.1039/B913785H

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