Highly enantioselective synthesis of tertiary alcohols: C2-symmetric N,N′-dioxide-Sc(III) complex promoted direct aldol reaction of α-ketoesters and diazoacetate esters

Fei Wang; Xiaohua Liu; Yulong Zhang; Lili Lin; Xiaoming Feng

doi:10.1039/B913520K

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Chemical Communications

Issue 47, 2009

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Highly enantioselective synthesis of tertiary alcohols: C₂-symmetric N,N′-dioxide-Sc(III) complex promoted direct aldol reaction of α-ketoesters and diazoacetate esters

Fei Wang , Xiaohua Liu , Yulong Zhang , Lili Lin and Xiaoming Feng

Chem. Commun., 2009, 7297-7299

DOI: 10.1039/B913520K
Received 07 Jul 2009, Accepted 16 Oct 2009
First published on the web 02 Nov 2009

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Abstract
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A C₂-symmetric N,N′-dioxide-Sc(III) complex has been developed to promote the asymmetric catalytic aldol reaction of α-ketoesters and diazoacetate esters to afford tertiary alcohols in good yields with excellent enantioselectivities.

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Fei Wang
Xiaohua Liu
Yulong Zhang
Lili Lin
Xiaoming Feng

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Chemical Communications

Highly enantioselective synthesis of tertiary alcohols: C₂-symmetric N,N′-dioxide-Sc(III) complex promoted direct aldol reaction of α-ketoesters and diazoacetate esters

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