Amide-based bifunctional organocatalysts in asymmetric reactions

Xiaohua Liu; Lili Lin; Xiaoming Feng

doi:10.1039/B913411E

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Chemical Communications

Issue 41, 2009

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Amide-based bifunctional organocatalysts in asymmetric reactions

Xiaohua Liu , Lili Lin and Xiaoming Feng

Chem. Commun., 2009, 6145-6158

DOI: 10.1039/B913411E
Received 06 Jul 2009, Accepted 11 Aug 2009
First published on the web 27 Aug 2009

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Abstract
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A series of amide-based bifunctional organocatalysts have been utilized in asymmetric reactions. Prolinamide analogues have been designed to catalyze asymmetric reactions via enamine intermediates with the assistance of tunable hydrogen bonding. In addition, the combination of various Lewis base functional groups, such as guanidine, N-oxide and phosphane, with an amide moiety have also constituted efficient bifunctional organocatalysts with unique reactivity and selectivity.

Abstract from Catalysts & Catalysed Reactions 2010

A review, with 47 references, describing recent advances in the use of amide-based bifunctional organocatalysts to achieve asymmetric catalysis of a number of different reactions.

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Chemical Communications

Amide-based bifunctional organocatalysts in asymmetric reactions

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