Molecular recognition of cationic phenothiazinium and phenoxazinium dyes with π-extended 2′-deoxyadenosine nucleotides

Karina Mondragón-Vásquez; Hugo Morales-Rojas

doi:10.1039/B913315A

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Chemical Communications

Issue 44, 2009

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Molecular recognition of cationic phenothiazinium and phenoxazinium dyes with π-extended 2′-deoxyadenosine nucleotides

Karina Mondragón-Vásquez and Hugo Morales-Rojas

Chem. Commun., 2009, 6726-6728

DOI: 10.1039/B913315A
Received 06 Jul 2009, Accepted 15 Sep 2009
First published on the web 06 Oct 2009

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Abstract
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N ⁶-(N′-Arylcarbamoyl)-2′-deoxyadenosine-H-phosphonates displayed molecular recognition towards cationic phenothiazinium and phenoxazinium dyes in aqueous solutions; studies have shown that binding is driven mainly by aromatic interactions and that size and shape-complementarity of the aromatic rings in host and guest provides selectivity.

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Synthetic procedures and characterization data, UV-vistitrations, ¹⁹F NMR spectra, modeling, and thermodynamic data
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Chemical Communications

Molecular recognition of cationic phenothiazinium and phenoxazinium dyes with π-extended 2′-deoxyadenosine nucleotides

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