Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

Xiaochen Wang; Zhuoyan Li; Michael P. Doyle

doi:10.1039/B913019E

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Chemical Communications

Issue 37, 2009

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Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

Xiaochen Wang , Zhuoyan Li and Michael P. Doyle

Chem. Commun., 2009, 5612-5614

DOI: 10.1039/B913019E
Received 01 Jul 2009, Accepted 14 Aug 2009
First published on the web 26 Aug 2009
This article is part of the collection: Selective Catalysis for Organic Synthesis

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Abstract
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Lewis bases, including reactant aldehydes, inhibit the rate of conversion for cycloaddition and those, like aldehydes or nitriles, cause a decrease in enantiocontrol due to the Lewis acidity of the activated complex.

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Chemical Communications

Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

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