Fluoride-enhanced lanthanide luminescence and white-light emitting in multifunctional Al3Ln2 (Ln = Nd, Eu, Yb) heteropentanuclear complexes

Hai-Bing Xu; Xiao-Ming Chen; Qi-Sheng Zhang; Li-Yi Zhang; Zhong-Ning Chen

doi:10.1039/B912474H

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Chemical Communications

Issue 47, 2009

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Fluoride-enhanced lanthanide luminescence and white-light emitting in multifunctional Al₃Ln₂ (Ln = Nd, Eu, Yb) heteropentanuclear complexes

Hai-Bing Xu , Xiao-Ming Chen , Qi-Sheng Zhang , Li-Yi Zhang and Zhong-Ning Chen

Chem. Commun., 2009, 7318-7320

DOI: 10.1039/B912474H
Received 25 Jun 2009, Accepted 15 Oct 2009
First published on the web 02 Nov 2009

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Multifunctional heteropentanuclear Al₃Ln₂ (Ln = Nd, Eu, Yb) clusters with a novel structure exhibit significantly fluoride-enhanced lanthanide emission intensity and lifetime in both solid state and solution as well as unusual white-light emitting for an Al₃Eu₂ complex.

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Detailed synthetic procedures and characterization forcompounds 2-4
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Hai-Bing Xu
Xiao-Ming Chen
Qi-Sheng Zhang
Li-Yi Zhang
Zhong-Ning Chen

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Chemical Communications

Fluoride-enhanced lanthanide luminescence and white-light emitting in multifunctional Al₃Ln₂ (Ln = Nd, Eu, Yb) heteropentanuclear complexes

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