Direct catalytic asymmetric aldol reaction of β-keto esters with formaldehyde promoted by a dinuclear Ni2-Schiff base complex

Shinsuke Mouri; Zhihua Chen; Shigeki Matsunaga; Masakatsu Shibasaki

doi:10.1039/B912380F

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Chemical Communications

Issue 34, 2009

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Direct catalytic asymmetric aldol reaction of β-keto esters with formaldehyde promoted by a dinuclear Ni₂-Schiff base complex

Shinsuke Mouri , Zhihua Chen , Shigeki Matsunaga and Masakatsu Shibasaki

Chem. Commun., 2009, 5138-5140

DOI: 10.1039/B912380F
Received 23 Jun 2009, Accepted 07 Jul 2009
First published on the web 24 Jul 2009
This article is part of the collection: Selective Catalysis for Organic Synthesis

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A homodinuclear Ni₂-Schiff base 1 complex (0.1–1 mol%) promoted the direct catalytic asymmetric aldol reaction of β-keto esters with formaldehyde, giving hydroxymethylated adducts in 94–66% ee.

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General experimental information, spectral data of newcompounds, and copies of NMR spectral data
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Chemical Communications

Direct catalytic asymmetric aldol reaction of β-keto esters with formaldehyde promoted by a dinuclear Ni₂-Schiff base complex

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