Issue 42, 2009
From the journal:

Chemical Communications

Sp–sp3 C–C bond formation viaFe(OTf)3/TfOH cocatalyzed coupling reaction of terminal alkynes with benzylic alcohols†

Shi-Kai Xiang,a   Li-He Zhanga  and  Ning Jiao*ab  

* Corresponding authors

a State Key Laboratory of Natural and Biomimetic Drugs, Peking University, School of Pharmaceutical Sciences, Peking University, Xue Yuan Rd. 38, Beijing 100191, China
E-mail: jiaoning@bjmu.edu.cn
Fax: (+86) 010-8280-5297
Tel: (+86) 010-8280-5297

b State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

An Fe(OTf)3/TfOH cocatalyzed sp–sp3 C–C bond formation through the coupling of benzylic alcohols with terminal alkynes in the absence of base has been developed. H2O is the sole by-product.

Graphical abstract: Sp–sp3 C–C bond formation viaFe(OTf)3/TfOH cocatalyzed coupling reaction of terminal alkynes with benzylic alcohols

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Article information

DOI
https://doi.org/10.1039/B911905A
Article type
Communication
Submitted
18 Jun 2009
Accepted
19 Aug 2009
First published
14 Sep 2009

Chem. Commun., 2009, 6487-6489

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Sp–sp3 C–C bond formation viaFe(OTf)3/TfOH cocatalyzed coupling reaction of terminal alkynes with benzylic alcohols

S. Xiang, L. Zhang and N. Jiao, Chem. Commun., 2009, 6487 DOI: 10.1039/B911905A

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