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Issue 36, 2009
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Ketoximes to N-substituted thioamides viaPSCl3 mediated Beckmann rearrangement

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Abstract

N-Substituted thioamides were accessed from ketoximes by utilising PSCl3 as a uniquely capable reagent to induce Beckmann rearrangement as well as to capture the intermediate nitrilium ion.

Graphical abstract: Ketoximes to N-substituted thioamides viaPSCl3 mediated Beckmann rearrangement

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Supplementary files

Publication details

The article was received on 17 Jun 2009, accepted on 03 Jul 2009 and first published on 28 Jul 2009


Article type: Communication
DOI: 10.1039/B911844F
Citation: Chem. Commun., 2009,0, 5409-5411
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    Ketoximes to N-substituted thioamides viaPSCl3 mediated Beckmann rearrangement

    U. Pathak, L. K. Pandey, S. Mathur and M. V. S. Suryanarayana, Chem. Commun., 2009, 0, 5409
    DOI: 10.1039/B911844F

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