Discovery and early development of squaraine rotaxanes

Jeremiah J. Gassensmith; Jeffrey M. Baumes; Bradley D. Smith

doi:10.1039/B911064J

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Chemical Communications

Issue 42, 2009

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Discovery and early development of squaraine rotaxanes

Jeremiah J. Gassensmith , Jeffrey M. Baumes and Bradley D. Smith

Chem. Commun., 2009, 6329-6338

DOI: 10.1039/B911064J
Received 05 Jun 2009, Accepted 17 Jul 2009
First published on the web 24 Aug 2009

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The chemical and photophysical properties of a fluorescent squaraine dye are greatly enhanced when it is mechanically encapsulated inside a tetralactam macrocycle. This feature article describes the synthesis, structure, and photophysical performance of first-generation squaraine rotaxanes, and shows how they can be used as fluorescent imaging probes and chemosensors.

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Chemical Communications

Discovery and early development of squaraine rotaxanes

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