Direct functionalization of benzylic C–Hs with vinyl acetates via Fe-catalysis

Chun-Xiao Song; Gui-Xin Cai; Thomas R. Farrell; Zhong-Ping Jiang; Hu Li; Liang-Bing Gan; Zhang-Jie Shi

doi:10.1039/B911031C

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Chemical Communications

Issue 40, 2009

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Direct functionalization of benzylic C–Hs with vinyl acetates via Fe-catalysis

Chun-Xiao Song , Gui-Xin Cai , Thomas R. Farrell , Zhong-Ping Jiang , Hu Li , Liang-Bing Gan and Zhang-Jie Shi

Chem. Commun., 2009, 6002-6004

DOI: 10.1039/B911031C
Received 04 Jun 2009, Accepted 12 Aug 2009
First published on the web 07 Sep 2009
This article is part of the collection: Selective Catalysis for Organic Synthesis and Peking University Centenary Celebrations

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Abstract
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Direct cross-coupling to construct sp³ C–sp³ C bonds via Fe-catalyzed benzylic C–H activation with 1-aryl vinyl acetate was developed.

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Supplementary Info

Experimental details, analytical and spectral data, and NMRspectra of compounds
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Chun-Xiao Song
Gui-Xin Cai
Thomas R. Farrell
Zhong-Ping Jiang
Hu Li
Liang-Bing Gan
Zhang-Jie Shi

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Chemical Communications

Direct functionalization of benzylic C–Hs with vinyl acetates via Fe-catalysis

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