Origin of the asymmetric induction in metallosalen-catalyzed reactions of aldehydes

Wojciech Chaładaj; Janusz Jurczak

doi:10.1039/B910473A

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Chemical Communications

Issue 44, 2009

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Origin of the asymmetric induction in metallosalen-catalyzed reactions of aldehydes

Wojciech Chaładaj and Janusz Jurczak

Chem. Commun., 2009, 6747-6749

DOI: 10.1039/B910473A
Received 28 May 2009, Accepted 17 Sep 2009
First published on the web 07 Oct 2009

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Abstract
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This study investigates, experimentally and computationally, the role played by the structure of the diamine moiety of salen chromium complexes in determining the catalyst conformational equilibrium and, in consequence, the direction of asymmetric induction in metallosalen-catalyzed reactions of aldehydes.

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Chemical Communications

Origin of the asymmetric induction in metallosalen-catalyzed reactions of aldehydes

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