Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

Ahmad Masarwa; Alois Fürstner; Ilan Marek

doi:10.1039/B910465H

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Chemical Communications

Issue 38, 2009

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Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

Ahmad Masarwa , Alois Fürstner and Ilan Marek

Chem. Commun., 2009, 5760-5762

DOI: 10.1039/B910465H
Received 28 May 2009, Accepted 07 Aug 2009
First published on the web 02 Sep 2009
This article is part of the collection: Selective Catalysis for Organic Synthesis

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Pd(II)- and Pt(II)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.

Abstract from Catalysts & Catalysed Reactions 2009

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Chemical Communications

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

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