Highly efficient catalytic hydrodehalogenation of polychlorinated biphenyls (PCBs)

Saïd Akzinnay; Fabrice Bisaro; Catherine S. J. Cazin

doi:10.1039/B910415A

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Chemical Communications

Issue 38, 2009

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Highly efficient catalytic hydrodehalogenation of polychlorinated biphenyls (PCBs)

Saïd Akzinnay , Fabrice Bisaro and Catherine S. J. Cazin

Chem. Commun., 2009, 5752-5753

DOI: 10.1039/B910415A
Received 27 May 2009, Accepted 20 Aug 2009
First published on the web 07 Sep 2009

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Abstract
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The hydrodehalogenation of polychlorinated phenyls and biphenyls (PCBs), catalysed by palladium N-heterocyclic carbene complexes, proceeds with excellent yields, at very low catalyst loadings and at room temperature, using isopropanol as the hydrogen source and NaOH as the base.

Abstract from Catalysts & Catalysed Reactions 2009

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Procedures for hydrodehalogenation, synthesis of chlorinatedbiphenyl substrates and related ¹³C{¹H} NMR spectra
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Chemical Communications

Highly efficient catalytic hydrodehalogenation of polychlorinated biphenyls (PCBs)

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