The commensurate modulated structure of the metastable state in spin crossover complex [Fe(abpt)2(NCS)2]

Chou-Fu Sheu; Szu-Miao Chen; Shih-Chi Wang; Gene-Hsiang Lee; Yi-Hung Liu; Yu Wang

doi:10.1039/B910378C

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Chemical Communications

Issue 48, 2009

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The commensurate modulated structure of the metastable state in spin crossover complex [Fe(abpt)₂(NCS)₂]

Chou-Fu Sheu , Szu-Miao Chen , Shih-Chi Wang , Gene-Hsiang Lee , Yi-Hung Liu and Yu Wang

Chem. Commun., 2009, 7512-7514

DOI: 10.1039/B910378C
Received 27 May 2009, Accepted 21 Oct 2009
First published on the web 09 Nov 2009

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Abstract
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Two new polymorphs (C and D) of [t-Fe(abpt)₂(NCS)₂] are characterized, a commensurate modulated structure with the c axis tripled in the thermally quenched metastable high spin state at 25 K is found in polymorph C.

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Chou-Fu Sheu
Szu-Miao Chen
Shih-Chi Wang
Gene-Hsiang Lee
Yi-Hung Liu
Yu Wang

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Chemical Communications

The commensurate modulated structure of the metastable state in spin crossover complex [Fe(abpt)₂(NCS)₂]

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