Pd–silicalite-1 composite membrane for direct hydroxylation of benzene

Yu Guo; Xiongfu Zhang; Hongye Zou; Haiou Liu; Jinqu Wang; King Lun Yeung

doi:10.1039/B910168C

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Chemical Communications

Issue 39, 2009

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Pd–silicalite-1 composite membrane for direct hydroxylation of benzene

Yu Guo , Xiongfu Zhang , Hongye Zou , Haiou Liu , Jinqu Wang and King Lun Yeung

Chem. Commun., 2009, 5898-5900

DOI: 10.1039/B910168C
Received 22 May 2009, Accepted 23 Jul 2009
First published on the web 18 Aug 2009

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Abstract
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Pd membranes of excellent stability and flux were prepared with multi-legged anchors by electroless plating of Pd on a porous support modified by a zeolite barrier layer containing Pd seeds; these membranes provide stable phenol production by direct hydroxylation of benzene.

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Pressure exchanging cycling test, formation mechanism of thePd membrane and analysis of membrane configuration
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Yu Guo
Xiongfu Zhang
Hongye Zou
Haiou Liu
Jinqu Wang
King Lun Yeung

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Chemical Communications

Pd–silicalite-1 composite membrane for direct hydroxylation of benzene

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