First hexanuclear copper(II) pyrophosphate through hydrolysis of phosphodiester with a dicopper complex

Shahulhameed Sabiah; Babu Varghese; Narasimha N. Murthy

doi:10.1039/B910094F

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First hexanuclear copper(ii) pyrophosphate through hydrolysis of phosphodiester with a dicopper complex†

Shahulhameed Sabiah,‡*^a Babu Varghese^b and Narasimha N. Murthy^a

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^a Department of Chemistry, Indian Institute of Technology, Madras, India
E-mail: sabiahs@gmail.com

^b Sophisticated Analytical Instrumentation facility, Indian Institute of Technology, Madras, India

Abstract

Facile hydrolysis of a phosphodiester promoted by a dicopper bis(μ-hydroxo) complex containing a new biphenyl appended N-bidentate ligand led to the isolation of the first example of hexameric copper pyrophosphate through ‘in situ self assembly’.

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DOI: https://doi.org/10.1039/B910094F
Article type: Communication
Submitted: 21 May 2009
Accepted: 30 Jun 2009
First published: 06 Aug 2009

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Chem. Commun., 2009, 5636-5638

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First hexanuclear copper(II) pyrophosphate through hydrolysis of phosphodiester with a dicopper complex

S. Sabiah, B. Varghese and N. N. Murthy, Chem. Commun., 2009, 5636 DOI: 10.1039/B910094F

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Chemical Communications

First hexanuclear copper(ii) pyrophosphate through hydrolysis of phosphodiester with a dicopper complex†

Abstract

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First hexanuclear copper(II) pyrophosphate through hydrolysis of phosphodiester with a dicopper complex

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