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Issue 30, 2009
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One-step formation of fused tetracyclic skeletons from cyclohexene-diynes and carbon monoxide through Rh(I)-catalyzed [2 + 2 + 2 + 1] cycloaddition reaction

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Abstract

Rapid construction of 5-7-6-5 fused tetracyclic carbocycles and heterocycles from cyclohexene-diynes and CO has been achieved in one step through a Rh(I)-catalyzed [2 + 2 + 2 + 1] cycloaddition process.

Graphical abstract: One-step formation of fused tetracyclic skeletons from cyclohexene-diynes and carbon monoxide through Rh(i)-catalyzed [2 + 2 + 2 + 1] cycloaddition reaction

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Publication details

The article was received on 18 May 2009, accepted on 15 Jun 2009 and first published on 29 Jun 2009


Article type: Communication
DOI: 10.1039/B909781C
Citation: Chem. Commun., 2009, 4569-4571
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    One-step formation of fused tetracyclic skeletons from cyclohexene-diynes and carbon monoxide through Rh(I)-catalyzed [2 + 2 + 2 + 1] cycloaddition reaction

    J. J. Kaloko, Y. G. Teng and I. Ojima, Chem. Commun., 2009, 4569
    DOI: 10.1039/B909781C

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