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Issue 37, 2009
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Two diamino-substituted lithiocarbanions in one molecule

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Abstract

tert-Butyllithium deprotonates bis(3-methyl-1,3-diazacyclohex-1-yl)methane and its five-ring analogue regioselectively at both endocyclic NCH2N units; a deprotonation intermediate has been isolated and structurally characterised.

Graphical abstract: Two diamino-substituted lithiocarbanions in one molecule

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Publication details

The article was received on 14 May 2009, accepted on 23 Jul 2009 and first published on 20 Aug 2009


Article type: Communication
DOI: 10.1039/B909561F
Citation: Chem. Commun., 2009,0, 5558-5560
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    Two diamino-substituted lithiocarbanions in one molecule

    I. Kamps, A. Mix, R. J. F. Berger, B. Neumann, H. Stammler and N. W. Mitzel, Chem. Commun., 2009, 0, 5558
    DOI: 10.1039/B909561F

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