Recent extensions of the Morita–Baylis–Hillman reaction

Guang-Ning Ma; Jia-Jun Jiang; Min Shi; Yin Wei

doi:10.1039/B909405A

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Chemical Communications

Issue 37, 2009

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Recent extensions of the Morita–Baylis–Hillman reaction

Guang-Ning Ma , Jia-Jun Jiang , Min Shi and Yin Wei

Chem. Commun., 2009, 5496-5514

DOI: 10.1039/B909405A
Received 12 May 2009, Accepted 17 Jul 2009
First published on the web 13 Aug 2009

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Abstract
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Significant progress in the development of the Morita–Baylis–Hillman (MBH) reaction has been made in the past decade. Many new variations of the MBH reaction have been well exploited, affording unexpected products and novel cyclized adducts in some cases, known as “abnormal MBH reactions”. The formation of abnormal MBH adducts depends on the nature of the substrates and the employed catalytic system. This article will summarize recent advances in and mechanistic insights into such “abnormal” MBH reactions, including double-MBH reactions, sila-MBH reactions, abnormal aza-MBH reactions and tandem MBH pathways.

Abstract from Methods in Organic Synthesis 2010

A review, with 50 references, describing advances in the Morita–Baylis–Hillman reaction, focusing on research from the past decade.

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Chemical Communications

Recent extensions of the Morita–Baylis–Hillman reaction

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