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Issue 30, 2009
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Surprising isomer preference on IrIII, favoring facile H–C(sp3) bond cleavage

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Abstract

Species (PNP)Ir(X)(Y), where PNP = N(SiMe2CH2PtBu2)2−1 with X and Y halide, have a tBu group C–H bond heterolytically split by addition across the Ir–N bond.

Graphical abstract: Surprising isomer preference on IrIII, favoring facile H–C(sp3) bond cleavage

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Publication details

The article was received on 05 May 2009, accepted on 11 Jun 2009 and first published on 29 Jun 2009


Article type: Communication
DOI: 10.1039/B908954C
Citation: Chem. Commun., 2009,0, 4578-4580
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    Surprising isomer preference on IrIII, favoring facile H–C(sp3) bond cleavage

    N. P. Tsvetkov, M. F. Laird, H. Fan, M. Pink and K. G. Caulton, Chem. Commun., 2009, 0, 4578
    DOI: 10.1039/B908954C

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