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Issue 34, 2009
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Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction

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Abstract

This study describes a heteroligated, hemilabile PtII–P,S tweezer coordination complex that combines a chiral Jacobsen–Katsuki MnIII-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group.

Graphical abstract: Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction

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Publication details

The article was received on 05 May 2009, accepted on 25 Jun 2009 and first published on 16 Jul 2009


Article type: Communication
DOI: 10.1039/B908852K
Citation: Chem. Commun., 2009,0, 5121-5123
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    Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction

    P. A. Ulmann, A. B. Braunschweig, O. Lee, M. J. Wiester, G. C. Schatz and C. A. Mirkin, Chem. Commun., 2009, 0, 5121
    DOI: 10.1039/B908852K

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