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Issue 32, 2009
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Strong magnetic exchange coupling in the cyano-bridged coordination clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo)

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Abstract

Reaction of [(PY5Me2)V(MeCN)]2+ with [M(CN)6]3 (M = Cr, Mo) affords the star-like clusters [(PY5Me2)4V4M(CN)6]5+, exhibiting S = 9/2 ground states that are exceptionally well-isolated in energy.

Graphical abstract: Strong magnetic exchange coupling in the cyano-bridged coordination clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo)

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Publication details

The article was received on 07 May 2009, accepted on 23 Jun 2009 and first published on 14 Jul 2009


Article type: Communication
DOI: 10.1039/B908736B
Citation: Chem. Commun., 2009, 4829-4831
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    Strong magnetic exchange coupling in the cyano-bridged coordination clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo)

    D. E. Freedman, D. M. Jenkins and J. R. Long, Chem. Commun., 2009, 4829
    DOI: 10.1039/B908736B

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