Molecular tectonics: design of 2-D networks by simultaneous use of charge-assisted hydrogen and coordination bonds

Cristina Carpanese; Sylvie Ferlay; Nathalie Kyritsakas; Marc Henry; Mir Wais Hosseini

doi:10.1039/B908496G

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Chemical Communications

Issue 44, 2009

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Molecular tectonics: design of 2-D networks by simultaneous use of charge-assisted hydrogen and coordination bonds

Cristina Carpanese , Sylvie Ferlay , Nathalie Kyritsakas , Marc Henry and Mir Wais Hosseini

Chem. Commun., 2009, 6786-6788

DOI: 10.1039/B908496G
Received 29 Apr 2009, Accepted 14 Sep 2009
First published on the web 29 Sep 2009

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Using a combination of charge-assisted H- and coordination-bonds, a tetra component system composed of a dicationic and a dianionic organic tecton, Ag⁺ cation and XF₆⁻ (X= P, As, Sb) anion behaves as planned and leads to the formation of 2-D isostructural networks for which the energetic contributions of the two recognition events dominate the construction process.

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Cristina Carpanese
Sylvie Ferlay
Nathalie Kyritsakas
Marc Henry
Mir Wais Hosseini

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Chemical Communications

Molecular tectonics: design of 2-D networks by simultaneous use of charge-assisted hydrogen and coordination bonds

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