Issue 36, 2009
From the journal:

Chemical Communications

Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

Yan Zhangab  and  Jianbo Wang*ab  

* Corresponding authors

a Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China

b The State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China
E-mail: wangjb@pku.edu.cn
Fax: +8610-6275-1708

Abstract

The nucleophilicaddition reaction of diazo-compound derived anions or enolates with electrophilic C[double bond, length as m-dash]O and C[double bond, length as m-dash]N bonds have been summarized. The subsequent reactions of the addition products demonstrate diverse reactivities of the diazocarbonyl compounds bearing other functional groups and their potential in organic synthesis. Asymmetric catalysis is also possible with diazocarbonyl compounds as nucleophiles.

Graphical abstract: Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

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Article information

DOI
https://doi.org/10.1039/B908378B
Article type
Feature Article
Submitted
28 Apr 2009
Accepted
11 Jun 2009
First published
22 Jul 2009

Chem. Commun., 2009, 5350-5361

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Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

Y. Zhang and J. Wang, Chem. Commun., 2009, 5350 DOI: 10.1039/B908378B

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