Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

Yan Zhang; Jianbo Wang

doi:10.1039/B908378B

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Chemical Communications

Issue 36, 2009

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Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

Yan Zhang and Jianbo Wang

Chem. Commun., 2009, 5350-5361

DOI: 10.1039/B908378B
Received 28 Apr 2009, Accepted 11 Jun 2009
First published on the web 22 Jul 2009
This article is part of the collection: Peking University Centenary Celebrations

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Abstract
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The nucleophilic addition reaction of diazo-compound derived anions or enolates with electrophilic C [double bond, length as m-dash] O and CN bonds have been summarized. The subsequent reactions of the addition products demonstrate diverse reactivities of the diazocarbonyl compounds bearing other functional groups and their potential in organic synthesis. Asymmetric catalysis is also possible with diazocarbonyl compounds as nucleophiles.

Abstract from Methods in Organic Synthesis 2009

A review, with 48 references, summarising recent developments in nucleophilic addition reactions of anions or enolates derived from diazo compounds with electrophilic C [double bond, length as m-dash] O and CN bonds.

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Chemical Communications

Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

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