Formation of conjugated polymer brushes by surface-initiated catalyst-transfer polycondensation

S. Kyle Sontag; Nicholas Marshall; Jason Locklin

doi:10.1039/B907264K

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Chemical Communications

Issue 23, 2009

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Formation of conjugated polymer brushes by surface-initiated catalyst-transfer polycondensation

S. Kyle Sontag , Nicholas Marshall and Jason Locklin

Chem. Commun., 2009, 3354-3356

DOI: 10.1039/B907264K
Received 09 Apr 2009, Accepted 04 May 2009
First published on the web 15 May 2009

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Abstract
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Electroactive conjugated polymer brushes of poly(thiophene) and poly(phenylene) have been prepared via a surface-initiated Kumada-type polycondensation reaction, yielding films with a thickness up to 42 nm.

Supplementary Info

Detailed synthetic procedures, electrochemicalcharacterization of monolayers, and additional images ofbrushes
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Chemical Communications

Formation of conjugated polymer brushes by surface-initiated catalyst-transfer polycondensation

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