A calixarene-based copper-centered redox switch as a data storage prototype

Ulrich Darbost; Vanessa Penin; Erwann Jeanneau; Caroline Félix; Francis Vocanson; Christophe Bucher; Guy Royal; Isabelle Bonnamour

doi:10.1039/B907207A

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Chemical Communications

Issue 44, 2009

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A calixarene-based copper-centered redox switch as a data storage prototype

Ulrich Darbost , Vanessa Penin , Erwann Jeanneau , Caroline Félix , Francis Vocanson , Christophe Bucher , Guy Royal and Isabelle Bonnamour

Chem. Commun., 2009, 6774-6776

DOI: 10.1039/B907207A
Received 08 Apr 2009, Accepted 14 Sep 2009
First published on the web 28 Sep 2009

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Abstract
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A new copper redox molecular switch based on a calixarene possessing both imidazole- and quinoline-like fragments displays, through an exchange of ligands triggered by an electrochemical input, unexpected long-lasting stability of both the redox forms, as well as fast reversible cycling.

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Ulrich Darbost
Vanessa Penin
Erwann Jeanneau
Caroline Félix
Francis Vocanson
Christophe Bucher
Guy Royal
Isabelle Bonnamour

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Chemical Communications

A calixarene-based copper-centered redox switch as a data storage prototype

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