α,α-Dicyanoalkenes: versatile vinylogous nucleophiles for organic synthesis

Hai-Lei Cui; Ying-Chun Chen

doi:10.1039/B906201G

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Chemical Communications

Issue 30, 2009

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α,α-Dicyanoalkenes: versatile vinylogous nucleophiles for organic synthesis

Hai-Lei Cui and Ying-Chun Chen

Chem. Commun., 2009, 4479-4486

DOI: 10.1039/B906201G
Received 30 Mar 2009, Accepted 23 Apr 2009
First published on the web 27 May 2009

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α,α-Dicyanoalkenes are electron-deficient alkenes and inherently behave as electrophiles. Over the past five years some significant progress has been achieved by using α,α-dicyanoalkenes as vinylogous donors in C–C bond forming and other functionalisation reactions, especially for the construction of multifunctional products. In this feature article we will present the successful development of vinylogous reactions of α,α-dicyanoalkenes by our group and other groups.

Abstract from Methods in Organic Synthesis 2009

A review, with 46 references, of the use of the title compounds in vinylogous C–C bond forming reactions such as Michael additions.

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Chemical Communications

α,α-Dicyanoalkenes: versatile vinylogous nucleophiles for organic synthesis

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