Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3)

Velusamy Subbarayan; Joshua V. Ruppel; Shifa Zhu; Jason A. Perman; X. Peter Zhang

doi:10.1039/B905727G

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Chemical Communications

Issue 28, 2009

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Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN₃)

Velusamy Subbarayan , Joshua V. Ruppel , Shifa Zhu , Jason A. Perman and X. Peter Zhang

Chem. Commun., 2009, 4266-4268

DOI: 10.1039/B905727G
Received 23 Mar 2009, Accepted 26 May 2009
First published on the web 11 Jun 2009
This article is part of the collection: Selective Catalysis for Organic Synthesis

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A Co(II)-based catalytic system has been developed for asymmetric aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN₃) under mild conditions, forming the corresponding N-Tces-aziridines in high yields and excellent enantioselectivities.

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Velusamy Subbarayan
Joshua V. Ruppel
Shifa Zhu
Jason A. Perman
X. Peter Zhang

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Chemical Communications

Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN₃)

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