Copper-catalyzed cyclization reactions for the synthesis of alkaloids

Gwilherm Evano; Mathieu Toumi; Alexis Coste

doi:10.1039/B905601G

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Chemical Communications

Issue 28, 2009

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Copper-catalyzed cyclization reactions for the synthesis of alkaloids

Gwilherm Evano , Mathieu Toumi and Alexis Coste

Chem. Commun., 2009, 4166-4175

DOI: 10.1039/B905601G
Received 19 Mar 2009, Accepted 21 Apr 2009
First published on the web 18 May 2009

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Abstract
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Copper-mediated Ullmann type transformations have recently evolved as useful and valuable synthetic tools in organic synthesis. If newly developed catalytic systems are readily available, inexpensive, and tolerate most functional groups, they also provide new opportunities in natural product synthesis since they allow new and efficient retrosynthetic disconnections. They are also especially convenient for the development of straightforward cyclization and macrocyclization procedures. The present article showcases some examples of copper-catalyzed cyclization reactions for the synthesis of alkaloids we have recently developed.

Abstract from Methods in Organic Synthesis 2009

A review, with 48 references, of copper-mediated Ullmann type cyclisation and macrocyclisation reactions in alkaloid synthesis.

Abstract from Catalysts & Catalysed Reactions 2009

A review, with 48 references, of recent work from the authors' group on the use of copper-catalysed cyclisation reactions in alkaloid synthesis.

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Chemical Communications

Copper-catalyzed cyclization reactions for the synthesis of alkaloids

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