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Issue 25, 2009
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Azide ion recognition in water–CHCl3 using a chelating phosphonium borane as a receptor

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Abstract

In H2O–CHCl3, the phosphonium borane [ortho-(Mes2B)C6H4(PMePh2)]+ selectively complexes azide anions to afford ortho-(Mes2(N3)B)C6H4(PMePh2) in which the boron-bound azide anion is stabilized by an interaction with the adjacent phosphorus atom.

Graphical abstract: Azide ion recognition in water–CHCl3 using a chelating phosphonium borane as a receptor

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Publication details

The article was received on 16 Mar 2009, accepted on 06 May 2009 and first published on 27 May 2009


Article type: Communication
DOI: 10.1039/B905232A
Citation: Chem. Commun., 2009,0, 3729-3731
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    Azide ion recognition in water–CHCl3 using a chelating phosphonium borane as a receptor

    Y. Kim, T. W. Hudnall, G. Bouhadir, D. Bourissou and F. P. Gabbaï, Chem. Commun., 2009, 0, 3729
    DOI: 10.1039/B905232A

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