Azide ion recognition in water–CHCl3 using a chelating phosphonium borane as a receptor

Youngmin Kim; Todd W. Hudnall; Ghenwa Bouhadir; Didier Bourissou; François P. Gabbaï

doi:10.1039/B905232A

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Chemical Communications

Issue 25, 2009

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Azide ion recognition in water–CHCl₃ using a chelating phosphonium borane as a receptor

Youngmin Kim , Todd W. Hudnall , Ghenwa Bouhadir , Didier Bourissou and François P. Gabbaï

Chem. Commun., 2009, 3729-3731

DOI: 10.1039/B905232A
Received 16 Mar 2009, Accepted 06 May 2009
First published on the web 27 May 2009

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Abstract
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In H₂O–CHCl₃, the phosphonium borane [ortho-(Mes₂B)C₆H₄(PMePh₂)]⁺ selectively complexes azide anions to afford ortho-(Mes₂(N₃)B)C₆H₄(PMePh₂) in which the boron-bound azide anion is stabilized by an interaction with the adjacent phosphorus atom.

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Youngmin Kim
Todd W. Hudnall
Ghenwa Bouhadir
Didier Bourissou
François P. Gabbaï

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Chemical Communications

Azide ion recognition in water–CHCl₃ using a chelating phosphonium borane as a receptor

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