Issue 31, 2009
From the journal:

Chemical Communications

Solvent-modulated metamagnetism in a nickel(ii) coordination polymer with mixed azide and carboxylate bridges†

Wei-Wei Sun,a   Chun-Yan Tian,a   Xue-Hui Jing,a   Yan-Qin Wanga  and  En-Qing Gao*a  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China
E-mail: eqgao@chem.ecnu.edu.cn

Abstract

A novel 2D coordination polymer consisting of ferromagnetic Ni(II) chains with alternating double EO-azide bridges and (EO-azide)bis(carboxylate) triple bridges exhibits solvent-modulated metamagnetism, and the reversible dehydration/hydration processes are accompanied by significant changes in critical temperature, critical field and hysteresis.

Graphical abstract: Solvent-modulated metamagnetism in a nickel(ii) coordination polymer with mixed azide and carboxylate bridges

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Article information

DOI
https://doi.org/10.1039/B904068D
Article type
Communication
Submitted
26 Feb 2009
Accepted
11 Jun 2009
First published
01 Jul 2009

Chem. Commun., 2009, 4741-4743

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Solvent-modulated metamagnetism in a nickel(II) coordination polymer with mixed azide and carboxylate bridges

W. Sun, C. Tian, X. Jing, Y. Wang and E. Gao, Chem. Commun., 2009, 4741 DOI: 10.1039/B904068D

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