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Issue 22, 2009
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Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC–H vs.Si–O bond cleavage

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Abstract

A new application of zincate [(THF)Li(TMP)(tBu)Zn(tBu)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DlZn) of trimethyl(phenoxy)silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.

Graphical abstract: Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC–H vs.Si–O bond cleavage

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Publication details

The article was received on 19 Feb 2009, accepted on 02 Apr 2009 and first published on 20 Apr 2009


Article type: Communication
DOI: 10.1039/B903592C
Citation: Chem. Commun., 2009,0, 3240-3242
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    Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC–H vs.Si–O bond cleavage

    E. Hevia, A. R. Kennedy, J. Klett and M. D. McCall, Chem. Commun., 2009, 0, 3240
    DOI: 10.1039/B903592C

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