Boryl ligands and their roles in metal-catalysed borylation reactions

Li Dang; Zhenyang Lin; Todd B. Marder

doi:10.1039/B903098K

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Chemical Communications

Issue 27, 2009

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Boryl ligands and their roles in metal-catalysed borylation reactions

Li Dang , Zhenyang Lin and Todd B. Marder

Chem. Commun., 2009, 3987-3995

DOI: 10.1039/B903098K
Received 13 Feb 2009, Accepted 06 Apr 2009
First published on the web 18 May 2009

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Abstract
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In this feature article, we discuss selected recent aspects of metal boryl (M–BR₂) chemistry pertaining, in particular, to the role of late and post-transition metal boryl complexes in various catalytic processes. The exceptionally strong σ-donor properties of boryl ligands and their related nucleophilic behaviour are highlighted.

Abstract from Methods in Organic Synthesis 2009

A review, with 38 references, discussing recent developments in metal boryl chemistry, with a focus on the use of late- and post-transition metal boryl complexes in catalytic reactions.

Abstract from Catalysts & Catalysed Reactions 2009

A review, with 38 references, of recent developments in metal boryl chemistry in various catalytic processes.

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Chemical Communications

Boryl ligands and their roles in metal-catalysed borylation reactions

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