Issue 25, 2009
From the journal:

Chemical Communications

A Zn-based, pillared paddlewheel MOF containing free carboxylic acidsvia covalent post-synthesis elaboration†

Tendai Gadzikwa,a   Omar K. Farha,a   Karen L. Mulfort,ab   Joseph T. Hupp*a  and  SonBinh T. Nguyen*a  

* Corresponding authors

a Department of Chemistry and the Institute for Catalysis in Energy Processes, Northwestern University, 2145 Sheridan Road, Evanston, USA
E-mail: j-hupp@northwestern.edu, stn@northwestern.edu
Fax: +1 874-467-1425, 874-491-7713
Tel: +1 847-491-3504, 847-467-3347

b Division of Chemical Sciences and Engineering, Argonne National Laboratory, Argonne, USA

Abstract

A Zn-based, mixed-ligand (pillared paddlewheel), metal–organic framework (MOF) has been covalently and quantitatively decorated with free carboxylic acids to demonstrate the utility of covalent post-synthesis modification in the construction of otherwise inaccessible carboxy-functionalized MOFs.

Graphical abstract: A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration

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Article information

DOI
https://doi.org/10.1039/B823392F
Article type
Communication
Submitted
05 Jan 2009
Accepted
13 Apr 2009
First published
26 May 2009

Chem. Commun., 2009, 3720-3722

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A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration

T. Gadzikwa, O. K. Farha, K. L. Mulfort, J. T. Hupp and S. T. Nguyen, Chem. Commun., 2009, 3720 DOI: 10.1039/B823392F

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