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Issue 14, 2009
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Aromatic trifluoromethylation catalytic in copper

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Abstract

Cu(I)-diamine complexes were found to catalyse the trifluoromethylation of aryl iodides. In the presence of a small amount of CuX (X = Cl, Br, I) and 1,10-phenanthroline (phen), the cross-coupling reactions of iodoarenes with trifluoromethylsilanes proceeded smoothly to afford trifluoromethylated aromatics in good yields.

Graphical abstract: Aromatic trifluoromethylation catalytic in copper

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Publication details

The article was received on 24 Dec 2008, accepted on 30 Jan 2009 and first published on 23 Feb 2009


Article type: Communication
DOI: 10.1039/B823249K
Citation: Chem. Commun., 2009,0, 1909-1911
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    Aromatic trifluoromethylation catalytic in copper

    M. Oishi, H. Kondo and H. Amii, Chem. Commun., 2009, 0, 1909
    DOI: 10.1039/B823249K

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