Salan ligands assembled around chiral bipyrrolidine: predetermination of chirality around octahedral Ti and Zr centres

Ekaterina Sergeeva; Jacob Kopilov; Israel Goldberg; Moshe Kol

doi:10.1039/B823176A

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Chemical Communications

Issue 21, 2009

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Salan ligands assembled around chiral bipyrrolidine: predetermination of chirality around octahedral Ti and Zr centres

Ekaterina Sergeeva , Jacob Kopilov , Israel Goldberg and Moshe Kol

Chem. Commun., 2009, 3053-3055

DOI: 10.1039/B823176A
Received 24 Dec 2008, Accepted 18 Mar 2009
First published on the web 09 Apr 2009

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The first synthesis of Salan ligands assembled around the chiral 2,2′-bipyrrolidine backbone is described; as chelation to a metal can only occur via specific faces of the two pyrrolidine nitrogens, these ligands lead to predetermined chirality at metal centres of octahedral titanium and zirconium complexes.

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Chemical Communications

Salan ligands assembled around chiral bipyrrolidine: predetermination of chirality around octahedral Ti and Zr centres

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