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Issue 14, 2009
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Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

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Abstract

A pentavalent uranyl complex supported by a bulky dianionic tetradentate (ONNO)-type salan ligand has been prepared by direct synthesis from the iodide precursor {[UO2Py5][KI2Py2]}n, and displays high stability towards disproportionation and ligand dissociation but reactivity towards oxidizing substrates.

Graphical abstract: Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

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Publication details

The article was received on 28 Nov 2008, accepted on 28 Jan 2009 and first published on 19 Feb 2009


Article type: Communication
DOI: 10.1039/B821398D
Citation: Chem. Commun., 2009,0, 1843-1845
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    Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

    P. Horeglad, G. Nocton, Y. Filinchuk, J. Pécaut and M. Mazzanti, Chem. Commun., 2009, 0, 1843
    DOI: 10.1039/B821398D

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