Issue 12, 2009
From the journal:

Chemical Communications

Solvent dependent asymmetric hydrogenation with self-assembled catalysts: a combined catalytic, NMR- and IR-study†

Ivan A. Shuklov,a   Natalia V. Dubrovina,*b   Enrico Barsch,ac   Ralf Ludwig,ac   Dirk Michalika  and  Armin Börner*ab  

* Corresponding authors

a Leibniz-Institut für Katalyse an der Universität Rostock e.V., A.-Einstein-Str., 29a, Rostock, Germany
E-mail: armin.boerner@catalysis.de
Fax: +49 (0)381 1281 5202

b Institut für Chemie der Universität Rostock, A.-Einstein-Str. 3a, Rostock, Germany
E-mail: natalia.dubrovina@uni-rostock.de

c Institut für Chemie der Universität Rostock, Dr.-Lorenz-Weg 1, Rostock, Germany

Abstract

For the first time the hydrogen bond based structure of self-aggregated Rh–phosphine complexes in fluorinated alcohols was directly determined, which gives a rationale for the high enantioselectivity observed in the asymmetric hydrogenation.

Graphical abstract: Solvent dependent asymmetric hydrogenation with self-assembled catalysts: a combined catalytic, NMR- and IR-study

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Article information

DOI
https://doi.org/10.1039/B820730E
Article type
Communication
Submitted
19 Nov 2008
Accepted
08 Jan 2009
First published
26 Jan 2009

Chem. Commun., 2009, 1535-1537

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Solvent dependent asymmetric hydrogenation with self-assembled catalysts: a combined catalytic, NMR- and IR-study

I. A. Shuklov, N. V. Dubrovina, E. Barsch, R. Ludwig, D. Michalik and A. Börner, Chem. Commun., 2009, 1535 DOI: 10.1039/B820730E

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