Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates

Ryan E. Cowley; Nathan A. Eckert; Jérôme Elhaïk; Patrick L. Holland

doi:10.1039/B820620A

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Chemical Communications

Issue 13, 2009

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Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates

Ryan E. Cowley , Nathan A. Eckert , Jérôme Elhaïk and Patrick L. Holland

Chem. Commun., 2009, 1760-1762

DOI: 10.1039/B820620A
Received 18 Nov 2008, Accepted 21 Jan 2009
First published on the web 17 Feb 2009

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The metastable iron(III) imido species L^tBuFeNAd catalyzes transfer of the nitrene fragment NAd from an organic azide to isocyanides or CO, forming unsymmetrical carbodiimides or isocyanates.

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Chemical Communications

Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates

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