Issue 17, 2009
From the journal:

Chemical Communications

An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts

Sweety Singhal,a   Suman L. Jaina  and  Bir Sain*a  

* Corresponding authors

a Process Engineering Applied Chemistry and Biotechnology Division Indian Institute of Petroleum, Dehradun, India
E-mail: birsain@iip.res.in
Fax: 91-135-2660202
Tel: 91-135-2660071

Abstract

The first report on the use of vanadium-based catalysts for oxidative cyanation of tertiary amines with molecular oxygen in the presence of sodium cyanide and acetic acid to afford the corresponding α-aminonitriles in good to excellent yields is described.

Graphical abstract: An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts

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Article information

DOI
https://doi.org/10.1039/B820402K
Article type
Communication
Submitted
14 Nov 2008
Accepted
16 Feb 2009
First published
11 Mar 2009

Chem. Commun., 2009, 2371-2372

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An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts

S. Singhal, S. L. Jain and B. Sain, Chem. Commun., 2009, 2371 DOI: 10.1039/B820402K

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