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Issue 17, 2009
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An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts

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Abstract

The first report on the use of vanadium-based catalysts for oxidative cyanation of tertiary amines with molecular oxygen in the presence of sodium cyanide and acetic acid to afford the corresponding α-aminonitriles in good to excellent yields is described.

Graphical abstract: An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts

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Publication details

The article was received on 14 Nov 2008, accepted on 16 Feb 2009 and first published on 11 Mar 2009


Article type: Communication
DOI: 10.1039/B820402K
Citation: Chem. Commun., 2009,0, 2371-2372
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    An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts

    S. Singhal, S. L. Jain and B. Sain, Chem. Commun., 2009, 0, 2371
    DOI: 10.1039/B820402K

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