Exploring the pH dependence of viologen reduction by α-carbon radicals derived from Hcy and Cys

Dong Wang; William E. Crowe; Robert M. Strongin; Martha Sibrian-Vazquez

doi:10.1039/B819746F

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Chemical Communications

Issue 14, 2009

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Exploring the pH dependence of viologen reduction by α-carbon radicals derived from Hcy and Cys

Dong Wang , William E. Crowe , Robert M. Strongin and Martha Sibrian-Vazquez

Chem. Commun., 2009, 1876-1878

DOI: 10.1039/B819746F
Received 05 Nov 2008, Accepted 05 Feb 2009
First published on the web 03 Mar 2009

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Abstract
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The colorimetric reaction of homocysteine (HCy) with a series of viologen salts suggests a linear correlation between the mid-point reduction potential of Hcy-derived α-carbon radicals and pH.

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Experimental details and spectroscopic data of preparedviologens
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Chemical Communications

Exploring the pH dependence of viologen reduction by α-carbon radicals derived from Hcy and Cys

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