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Issue 7, 2009
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A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

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Abstract

When isolated in the high vacuum of an ESI-FTICR mass spectrometer, bowl-shaped metallo-supramolecular M6L4 assemblies undergo a surprising and mechanistically interesting intramolecular double cage contraction to yield smaller M3L2 cages.

Graphical abstract: A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

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Publication details

The article was received on 31 Oct 2008, accepted on 10 Dec 2008 and first published on 14 Jan 2009


Article type: Communication
DOI: 10.1039/B819412B
Citation: Chem. Commun., 2009,0, 785-787
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    A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

    B. Brusilowskij, S. Neubacher and C. A. Schalley, Chem. Commun., 2009, 0, 785
    DOI: 10.1039/B819412B

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