A metal–organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior

Mira Park; Dohyun Moon; Ji Woong Yoon; Jong-San Chang; Myoung Soo Lah

doi:10.1039/B818648K

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Chemical Communications

Issue 15, 2009

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A metal–organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior

Mira Park , Dohyun Moon , Ji Woong Yoon , Jong-San Chang and Myoung Soo Lah

Chem. Commun., 2009, 2026-2028

DOI: 10.1039/B818648K
Received 21 Oct 2008, Accepted 04 Feb 2009
First published on the web 26 Feb 2009

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Abstract
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A 3D chiral microporous metal–organic framework containing a nonanuclear cluster as a secondary building unit was prepared using a bent and rigid dicarboxylic ligand, 2,7-naphthalene dicarboxylic acid, and the zinc ion, where a nonanuclear cluster with potential exposed metal sites is in the form of a corner-sharing cyclic trimer of a tetrahedral Zn₄O motif.

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Experimental procedure, crystallographic details, TGA data,PXRD, IR spectra, and gas sorption data
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Mira Park
Dohyun Moon
Ji Woong Yoon
Jong-San Chang
Myoung Soo Lah

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Chemical Communications

A metal–organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior

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