Issue 6, 2009

A model study for the concise construction of the oxapentacyclic core of cortistatins through intramolecular Diels–Alder and oxidative dearomatization–cyclization reactions

Abstract

A unified strategy towards the facile construction of the [6.7.6.5] oxapentacyclic skeleton of cortistatins is reported, featuring intramolecular Diels–Alder (IMDA) and oxidative dearomatization–cyclization reactions as key steps.

Graphical abstract: A model study for the concise construction of the oxapentacyclic core of cortistatins through intramolecular Diels–Alder and oxidative dearomatization–cyclization reactions

Supplementary files

Article information

Article type
Communication
Submitted
03 Oct 2008
Accepted
11 Nov 2008
First published
09 Dec 2008

Chem. Commun., 2009, 662-664

A model study for the concise construction of the oxapentacyclic core of cortistatins through intramolecular Diels–Alder and oxidative dearomatization–cyclization reactions

L. Liu, Y. Gao, C. Che, N. Wu, D. Z. Wang, C. Li and Z. Yang, Chem. Commun., 2009, 662 DOI: 10.1039/B817376A

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