Bio-inspired arenecis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase

Yan Feng; Chun-yen Ke; Genqiang Xue; Lawrence Que

doi:10.1039/B817222F

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Chemical Communications

Issue 1, 2009

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Bio-inspired arenecis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase

Yan Feng , Chun-yen Ke , Genqiang Xue and Lawrence Que

Chem. Commun., 2009, 50-52

DOI: 10.1039/B817222F
Received 02 Oct 2008, Accepted 30 Oct 2008
First published on the web 12 Nov 2008

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Reported in this paper is the first example of a biomimetic iron complex, ([Fe^II(TPA)(NCMe)₂]²⁺ (TPA = tris(2-pyridylmethyl)amine), that catalyses the cis-dihydroxylation of an aromatic double bond, mimicking the action of the non-haem iron enzymenaphthalene dioxygenase and shedding light on its possible mechanism of action.

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Chemical Communications

Bio-inspired arenecis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase

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