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Issue 5, 2009
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Synergic asymmetric organocatalysis (SAOc) of Cinchonaalkaloids and secondary amines in the synthesis of bicyclo[2.2.2]octan-2-ones

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Abstract

A synergistic effect between chiral secondary and tertiary amines gives access to bicyclo[2.2.2]octan-2-ones with up to 90% ee and >10 : 1 dr.

Graphical abstract: Synergic asymmetric organocatalysis (SAOc) of Cinchonaalkaloids and secondary amines in the synthesis of bicyclo[2.2.2]octan-2-ones

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Publication details

The article was received on 22 Sep 2008, accepted on 19 Nov 2008 and first published on 08 Dec 2008


Article type: Communication
DOI: 10.1039/B816550E
Citation: Chem. Commun., 2009,0, 597-599
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    Synergic asymmetric organocatalysis (SAOc) of Cinchonaalkaloids and secondary amines in the synthesis of bicyclo[2.2.2]octan-2-ones

    M. Bella, D. M. S. Schietroma, P. P. Cusella, T. Gasperi and V. Visca, Chem. Commun., 2009, 0, 597
    DOI: 10.1039/B816550E

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