Low pressure CO2 to dimethyl carbonate by the reaction with methanol promoted by acetonitrile hydration

Masayoshi Honda; Atsushi Suzuki; Begum Noorjahan; Ken-ichiro Fujimoto; Kimihito Suzuki; Keiichi Tomishige

doi:10.1039/B909610H

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Low pressure CO₂ to dimethyl carbonate by the reaction with methanol promoted by acetonitrile hydration†

Masayoshi Honda,^a Atsushi Suzuki,^a Begum Noorjahan,^a Ken-ichiro Fujimoto,^b Kimihito Suzuki^b and Keiichi Tomishige*^ac

Author affiliations

* Corresponding authors

^a Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1, Tennodai, Tsukuba, Ibaraki 305-8573, Japan
E-mail: tomi@tulip.sannet.ne.jp
Fax: +81 29-853-5030

^b Nippon Steel Corporation, Advanced Technology Research Laboratories 20-1, Shintomi, Futtsu, Chiba 293-8511, Japan

^c International Center for Materials Nanoarchitectonics Satellite (MANA), National Institute of Materials Science (NIMS) and University of Tsukuba, 1-1-1, Tennodai, Tsukuba, Ibaraki 305-8573, Japan

Abstract

CeO₂ catalysts catalyze the reaction of methanol with low pressure CO₂ to form dimethyl carbonate and the reaction was promoted by the combination with acetonitrile hydration over CeO₂.

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Supplementary files

Activity test details and XRD patterns PDF (314K)

Article information

DOI: https://doi.org/10.1039/B909610H
Article type: Communication
Submitted: 14 May 2009
Accepted: 28 May 2009
First published: 18 Jun 2009

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Chem. Commun., 2009, 4596-4598

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Low pressure CO₂ to dimethyl carbonate by the reaction with methanol promoted by acetonitrile hydration

M. Honda, A. Suzuki, B. Noorjahan, K. Fujimoto, K. Suzuki and K. Tomishige, Chem. Commun., 2009, 4596 DOI: 10.1039/B909610H

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Chemical Communications