Reaction of Ni(0) in the presence of iodoarylethers 1 leads, after syn intramolecular carbonickelation of the triple bond, to nucleophilic vinylnickels which can be trapped, in a tandem process, by various electrophiles introduced at the onset of the reaction.
M. Durandetti, L. Hardou, M. Clément and J. Maddaluno, Chem. Commun., 2009, 4753 DOI: 10.1039/B902095K
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