Issue 16, 2009
From the journal:

Chemical Communications

Unexpected nucleophilic behaviour of free-radicals generated from α-iodoketones†

Corinne De Dobbeleer,a   Jiří Pospíšil,a   Freija De Vleeschouwer,b   Frank De Proftb  and  István E. Markó*a  

* Corresponding authors

a Université catholique de Louvain, Département de Chimie, Bâtiment Lavoisier, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium
E-mail: istvan.marko@uclouvain.be
Fax: +32 1047 2788
Tel: +32 1047 8773

b Eenheid Algemene Chemie (ALGC), Vrije Universiteit Brussel (VUB), Faculteit Wetenschappen, Pleinlaan 2, 1050 Brussels, Belgium

Abstract

The unexpected nucleophilic reactivity of free-radicals generated from α-iodoketones is reported; two different procedures, either employing tin or the more environmentally acceptable ethylsulfone-based coupling reagent 5c have been developed.

Graphical abstract: Unexpected nucleophilic behaviour of free-radicals generated from α-iodoketones

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Article information

DOI
https://doi.org/10.1039/B901943J
Article type
Communication
Submitted
29 Jan 2009
Accepted
05 Mar 2009
First published
19 Mar 2009

Chem. Commun., 2009, 2142-2144

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Unexpected nucleophilic behaviour of free-radicals generated from α-iodoketones

C. De Dobbeleer, J. Pospíšil, F. De Vleeschouwer, F. De Proft and I. E. Markó, Chem. Commun., 2009, 2142 DOI: 10.1039/B901943J

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